Tracing the Evolution of Martian Volatiles
Imagine a Mars unlike the one we know today. Billions of years ago, rivers carved valleys across its surface, emptying into vast oceans under a protective atmosphere. Today, it's a frozen, arid desert. What happened?
For decades, evidence has mounted that Mars once hosted significant liquid water. Geological features including ancient riverbeds, massive canyons, and what appear to be ocean shorelines paint a picture of a watery past 7 .
A recent groundbreaking study from the University of Arkansas strengthened this case by identifying geological evidence of ancient river backwater zones—areas where rivers slow down as they approach a large body of water. The presence of these features, along with mature deltas, provides "strong evidence that large rivers once flowed on Mars and emptied into an ocean before the surface of the planet dried up billions of years ago" 1 .
So, what caused the dramatic climate shift? The current scientific consensus points to the loss of Mars' protective magnetic field. Unlike Earth, Mars lost its global magnetic field early in its history, leaving its atmosphere vulnerable to the solar wind—a constant stream of charged particles from the Sun 7 . This resulted in the atmosphere being stripped away over billions of years.
Mars once had enough water to form a global ocean estimated to be about 137 meters deep 7 .
The solar wind stripped away Mars' atmosphere after it lost its magnetic field protection.
While Mars' surface water is largely gone, the planet is not entirely dry. Scientists have identified at least four major reservoirs where water and other volatiles persist today, each with distinct characteristics 7 .
Today's Martian atmosphere is thin, composed mainly of CO₂, and contains only trace amounts of water vapor. It is highly enriched in "heavier" isotopes.
The most visible water reservoir today, Mars' polar caps are a mixture of water ice and frozen CO₂. It is estimated that the water stored could form a global ocean about 20 meters deep 7 .
A significant amount of water is likely locked away in the Martian crust as ice in the shallow subsurface, as well as in clay minerals and hydrated salts.
Deep within Mars lies a final reservoir of water and volatiles. Analysis of Martian meteorites suggests the mantle was once much richer in water.
While mapping water reservoirs is crucial, the ultimate question is whether Mars ever hosted life. A key step is finding organic molecules—the carbon-based building blocks of life. One of the most important experiments in this search was conducted by the Curiosity rover on Mars, analyzing a rock sample named "Cumberland."
Curiosity used its drill to pulverize the rock into a fine powder.
The powdered rock was delivered to the rover's onboard mini-lab, the Sample Analysis at Mars (SAM) instrument suite.
Inside SAM, the sample was heated to high temperatures in an oven. This process caused the rock to release gases.
The released gases were passed through a gas chromatograph, which separated the different molecules. A mass spectrometer then measured their masses, acting as a molecular "weighing scale" to identify them 2 .
The Curiosity rover collected and analyzed the Cumberland sample in Gale Crater, an ancient lakebed ideal for preserving organic material 2 .
The SAM instrument detected significant amounts of decane, undecane, and dodecane—organic molecules made of chains of 10, 11, and 12 carbon atoms, respectively. These were the largest organic molecules ever found on Mars at the time 2 .
Scientists hypothesized that these compounds were fragments that broke off from even larger molecules during heating. Working backward, they concluded the parent molecules were likely fatty acids, specifically undecanoic acid, dodecanoic acid, and tridecanoic acid 2 .
| Tool / Material | Function in Research | Example of Use |
|---|---|---|
| Inverted Ridges | Acts as a natural "cast" of ancient rivers, preserving their course and structure after the surrounding terrain erodes away 1 . | Used to map the flow and extent of ancient river systems on Mars from orbital data. |
| Sedimentary Mudstone | A fine-grained rock that forms in calm water environments (like lakebeds), ideal for trapping and preserving organic molecules and chemical clues to past habitability 2 . | Drilled by Curiosity rover to analyze for organics and minerals formed in water. |
| Gas Chromatograph-Mass Spectrometer (GC-MS) | The workhorse instrument for identifying unknown organic compounds. It separates a complex mixture (GC) and then identifies each component by its molecular mass (MS) 2 . | The core of the SAM instrument on Curiosity, used to detect large organic molecules in the Cumberland sample. |
| Isotopic Ratios | Act as a chemical "fingerprint" to trace the history of atmospheric loss and water-rock interactions. Lighter isotopes escape to space more easily, enriching the heavier ones left behind 7 . | Measured by rovers and orbiters to quantify how much of the Martian atmosphere has been lost over time. |
| Martian Meteorites | Provide actual pieces of Mars for analysis in Earth-based labs, allowing for more precise measurement of volatile content and isotopic composition than is possible with rover-based instruments 7 . | Studied to understand the volatile content of the Martian mantle and crust, and to identify delivered organic matter. |
NASA's Perseverance rover is now collecting pristine rock samples from Jezero Crater, an ancient river delta. A recent analysis revealed compelling potential biosignatures 6 .
NASA and ESA are planning to bring carefully selected samples back to Earth in the 2030s. Once in terrestrial laboratories, they can be analyzed with instruments far more powerful than anything that can be sent to Mars 2 .
China's planned Tianwen-3 mission also aims to return Martian samples, focusing on both ancient volcanic rocks and sedimentary layers to build a more complete picture 7 .
By studying these precious materials, scientists hope to finally answer the enduring questions: Was Mars ever alive? And what does its dramatic climate change tell us about the fate of our own planet?
The great vanishing act of the Martian oceans is a planetary puzzle we are closer than ever to solving.
References will be listed here in the final version.